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Strategic Stereoselective Halogen (F, Cl) Insertion: A Tool to Enhance Supramolecular Properties in Polyols

Abstract : To improve the supramolecular properties of organic compounds, chemists continuously need to identify new tools. Herein, the influence of the stereoselective insertion of halogen atoms (F or Cl) on different supramolecular properties is analyzed. Inserting anti-halohydrins in polyols considerably strengthens the H-bonding networks and other supramolecular interactions. This behavior resulted in improved anion binding, H-bonding catalysis, or organogel properties of the designed polyols with strong perspectives for applications in other classes of substrates.
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Submitted on : Thursday, November 28, 2019 - 2:51:18 PM
Last modification on : Sunday, June 26, 2022 - 2:43:47 AM
Long-term archiving on: : Saturday, February 29, 2020 - 5:21:53 PM

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Céline Sperandio, Guilhem Quintard, Jean-Valère Naubron, Michel Giorgi, Mehdi Yemloul, et al.. Strategic Stereoselective Halogen (F, Cl) Insertion: A Tool to Enhance Supramolecular Properties in Polyols. Chemistry - A European Journal, Wiley-VCH Verlag, 2019, 25 (66), pp.15098-15105. ⟨10.1002/chem.201902983⟩. ⟨hal-02384701⟩

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