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Mossbauer spectroscopic and computational investigation of an iron cyclopentadienone complex

Abstract : (Cyclopentadienone)iron carbonyl complexes have recently received particular attention for their use as catalysts in hydrogenation or transfer hydrogenation reactions including the N-alkylation of amines with alcohols. This is due to their easy synthesis from simple and cheap materials, air and water stabilities, and the crucial metal-ligand cooperation giving rise to unique catalytic properties. Here, we report a Mossbauer spectroscopic and computational investigation of such a complex and its corresponding activated species for dehydrogenation and hydrogenation reactions. This study affords a deeper understanding of the species formed by the reaction with Me$_3$NO and their distribution upon the added amount of an oxidant.
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Submitted on : Thursday, November 18, 2021 - 4:21:53 PM
Last modification on : Sunday, June 26, 2022 - 3:19:59 AM
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Ikram Yagoub, Martin Clémancey, Pierre-Alain Bayle, Adrien Quintard, Guillaume Delattre, et al.. Mossbauer spectroscopic and computational investigation of an iron cyclopentadienone complex. Inorganic Chemistry, American Chemical Society, 2021, 60 (15), pp.11192-11199. ⟨10.1021/acs.inorgchem.1c01155⟩. ⟨hal-03326124⟩

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